Biomimetic synthesis of (-)-longithorone A.
نویسندگان
چکیده
An enantioseletive, biomimetic synthesis of (-)-longithorone A has been achieved using an intermolecular/transannular Diels-Alder sequence which provides some support for the proposed biosynthesis. The cycloaddition precursors were two [12]-paracyclophanes that were constructed with atropisomer control during ene-yne metathesis macrocyclizations.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 124 5 شماره
صفحات -
تاریخ انتشار 2002